Chrome plating is a type of popularly used finishing method for various applications. There are many common things in our life are plated with a chrome coating.
Chrome coating parts are usually bright, wear-resistant and rust-proof. So, what is chrome plating and what influence does it have?
This article will introduce everything you should know about chrome plating.
Key Takeaways:
Chrome plating, also known as chromium plating or chrome electroplating, is a surface finishing technology that deposits a layer of chromium onto a metal or plastic surface through an electrolytic process.
The chromium itself is a type of silver-white metal with good hardness and corrosion resistance.
Chrome coating can provide the plated parts with decorative appeal, enhanced surface hardness, and excellent corrosion resistance.
Chrome plating is commonly used across various industries like CNC machining to improve the quality and performance of the plated parts.
Chromium is discovered to be able to serve as a protective coating in the early 20th century. And in the 1920s scientists developed chrome electroplating technique. Then chrome plating came into commerce for its appealing appearance and excellent resistance to rust and abrasion.
With continuous development, chrome plating made progress with emergence of different types such as hard chrome and decorative chrome, meeting specific industry requirements.
Nowadays, chrome plating is still one of the most popular finishing methods in manufacturing, making machining components much more durable and attractive.
This part will introduce what materials and tools are needed for chrome plating, which is important for the whole plating process. In addition, those key parameters also counts significantly.
The process of chrome plating can be divided into three main procedures, including pre-process, electroplating of chrome, and post-process. And these three procedures cover certain detailed steps.
Pre-process: The purpose of pre-process is to make the surface of parts completely clean and properly smooth, thus to make the coating stably plated on the surface. It is the essentially primary procedure since any oil, oxide, or impurity would cause blistering, peeling, or spotting in the final coating.
For plastic, a thin conductive metal layer(usually copper or nickel) should be plated by electroless process first.
Chrome Electroplating: After pre-process, the part is ready to be electroplated.
Under the influence of direct current (DC), chromate ions in the electrolyte would be reduced at the cathode and deposit to be a chrome coating.
Post-process: It is usually for cleaning and special treatment.
For great quality and desire performance, it is essential to carefully monitor and control multiple key parameters during the chrome plating process. These factors directly determine the corrosion resistance, hardness, appearance, and abrasion resistance etc. The critical parameters during chrome plating are as follows.
There are various types of chrome plating in manufacturing. Each of them would provide specific functions. It is critical to know them clearly and use them properly. This session will introduce the main types of chrome plating from function, plating solution, and coating structure.
Decorative chrome plating is primarily used to improve the appearance of surfaces. With a bright, shiny, and reflective finish, decorative chrome plating makes the surfaces attractive.
Decorative chrome plating can provide basic corrosion resistance and abrasion resistance. But its primary function is decoration.
Hard chrome plating, also known as wear-resistant chrome plating or engineering chrome plating, refers to a thick chromium coating with high hardness and excellent wear resistance. Compared with decorative chrome plating commonly seen in daily life, hard chrome plating is primarily to enhance the surface performance of metal components, rather than merely for aesthetic appeal.
Method 1. Use chromium plating solutions containing fluorides or organic additives to promote increased internal stress and induce crack formation.
Method 2. Turn the current density high and temperature low to elevate internal stress within the coating, thus encouraging natural cracking.
Method 3. Induce cracks after plating through heat treatment or mechanical stress.
While under a microscope, the surface reveals an extremely fine, continuous, and irregular network of micro-cracks. And the crack widths are extremely narrow, typically less than 0.5 micrometers.
Table of Comparison: Porous VS Micro-porous VS Micro-cracked Chrome Plating | |||
Feature | Porous Chrome Plating | Micro-porous Chrome Plating | Micro-cracked Chrome Plating |
Pore/Crack Size
| tens to hundreds μm
| 10–30 μm, uniformly distributed | Crack width<1μm, depth<10μm, network pattern |
Density | Sparse | High(10⁴-10⁵pores/cm²) | High(400–1000 cracks/cm) |
Roughness | High(Ra > 1 μm) | Medium(Ra 0.2–0.8μm) | Low(Ra 0.1–0.4 μm) |
Oil Retention | ★★★★☆(Large pores hold more oil) | ★★★★☆(Uniform pores, even oil retention) | ★★★☆☆(Shallow cracks, limited oil retention) |
Wear Resistance
| ★★★☆☆(Pore edges prone to spalling) | ★★★★☆(Uniform structure, good wear resistance) | ★★★★★(Dense layer, stress-relieving cracks) |
Anti-Galling Property | ★★★★☆ | ★★★★☆ | ★★★★★ |
Load Bearing Capacity
| ★★☆☆☆(Pores act as stress concentrators)
| ★★★☆☆ | ★★★★☆(Micro-cracks disperse stress) |
Suitable Speed Range | Low speed, heavy load
| Medium to high speed | High speed, high load |
Hexavalent chrome plating is a traditional chromium plating process that has the longest history. Its plating bath typically contains chromic anhydride(CrO₃) as the main ingredient.
① Bath Composition: Chromic acid formed by dissolving chromic anhydride in water and catalyst(typically sulfate ions).
② Cathode Reaction: During the electroplating process, hexavalent chromium ions (Cr⁶⁺) in the solution are reduced at the cathode surface to deposit metallic chromium (Cr⁰).
③ Mature Technology: In use for over 80 years. The process is mature and easy to operate.
④ Bright Appearance: Hexavalent chromium plating is silvery white with highly bright gloss and excellent mirror finish.
⑤ Very Low Current Efficiency: Only 10–15% of electrical energy is used for chromium deposition, while most energy is consumed for hydrogen gas evolution.
① High hardness (800–1000 HV).
② Excellent wear and corrosion resistance.
③ Stable bath chemistry with relatively simple maintenance.
④ Thicker Coating
① High Toxicity: Hexavalent chromium (Cr⁶⁺) is a recognized potent carcinogen, posing severe damage to human health and the environment.
② Strict Environmental Regulations: Globally restricted or banned under regulations such as the EU’s RoHS, REACH, and ELV directives.
③ High Costs for Disposal: The wastewater and exhaust gases generated during production require expensive and complex disposal to meet discharge standards.
Developed as a replacement for hexavalent chromium plating, trivalent chromium plating has become the mainstream choice for decorative applications.
① Bath Composition: Trivalent chromium salts such as chromium chloride or chromium sulfate, complexing agents, conductive salts, and additives.
② Cathode Reaction: Trivalent chromium ions (Cr³⁺) are directly reduced at the cathode to deposit metallic chromium (Cr⁰).
③Environmental Advantage: Toxicity of trivalent chromium is approximately 1% that of hexavalent chromium, making it significantly more environmentally friendly.
④ Gentle Appearance: Early trivalent chromium coating is bluish-white with gentle gloss. But recent advancements in additives have enabled them to closely match the appearance of hexavalent chromium.
① Environmentally Friendliness: Trivalent chrome coating is the primary alternative to hexavalent chromium plating, compliant with international environmental regulations.
② Excellent Dispersibility: Trivalent chromium coating can be deposited more uniform, especially suitable for complex geometries.
③ Higher Current Efficiency: Up to 25%, offering significant energy savings.
① Lower coating hardness (500–700 HV), unsuitable for conditions requiring high wear resistance.
② Limited achievable thickness
③ The bath is sensitive to metallic impurities, requiring more stringent maintenance and control.
Divalent chromium plating is developed to overcome certain limitations of trivalent chromium plating.
① Bath Composition: Chloride-based solutions containing divalent chromium ions (Cr²⁺). Cr²⁺ is highly unstable and must be stabilized within specially formulated plating baths.
② Cathode Reaction: Divalent chromium ions (Cr²⁺) are directly reduced at the cathode to deposit metallic chromium (Cr⁰).
③ Cutting-Edge Technology: Currently a major focus of research and development in the chromium plating field.
① More Environmentally Friendly: Divalent chromium exhibits even lower toxicity than trivalent chromium.
② Very High Current Efficiency: More than 60%, offering exceptional energy savings.
③ High Deposition Rate: The production efficiency is much higher.
① Immature Technology: Cr²⁺ ions in the bath are highly easy to become Cr³⁺ by oxidation. It is still a challenge to make it stable.
② High Cost: The bath formulations are complex and expensive to maintain.
③ Limited Application: Divalent chrome plating remains primarily in the laboratory R&D now, not yet widely commercialized.
Table of Comparison: Hexavalent VS Trivalent VS Divalent Chrome Plating | |||
Feature | Hexavalent Chrome Plating | Trivalent Chrome Plating | Divalent Chrome Plating |
Chromium Ion | Cr⁶⁺ | Cr³⁺ | Cr²⁺ |
Toxicity | High(Carcinogenic) | Low | Extremely Low |
Environmental Friendliness | Very Poor, Strictly Restricted | Good, Mainstream Replacement | Excellent, Future Direction |
Hardness | High (800-1000 HV) | Medium (500-700 HV) | —— |
Current Efficiency | Very Low (10-15%) | Medium (~25%) | Very High (>60%) |
Coating Color | Bright White | Gentle Bluish-White | —— |
Coverage | Good | Better | —— |
Thickness | Able to be very thick | Thin (<1μm) | —— |
Technology | Very Mature | Less Mature | R&D Phase, Immature |
3.3.1 Thin Dense Chrome Plating
Thin Dense Chrome Plating is an electroplated chromium process with excellent performance such as thinner and denser coating, superior adhesion, and enhanced corrosion and wear resistance.
By using specialized chromium baths, this electroplating process can deposit thinner coating. And the high density is due to strict control of plating parameter such as slightly lower temperature.
Thin dense chromium plating is widely used in industries with extremely demanding surface performance requirements, such as aerospace, automotive, tooling and molding, hydraulic systems, and defense.
① Extremely Thin Coating: The thickness of thin dense chrome coating typically ranges from 2.5 to 25 micrometers, substantially thinner than conventional hard chrome coating(typically 25–250 micrometers).
② Dense Microstructure: The coating structure is dense and without micro cracks compared with traditional hard chrome coating. Its dense microstructure and extremely low porosity can effectively block the penetration of corrosive media.
③ Low Friction Coefficient: The friction coefficient of thin dense chrome plating can be as low as 0.09, making the coating significantly self-lubricating. With plating of thin dense chrome coating, the friction and wear can be beneficially reduced and it can also prevent galling or seizing between components.
① Excellent Corrosion Resistance: Due to its dense structure and minimal micro-cracks, thin dense chrome plating exhibits significantly improved corrosion resistance. In salt spray testing such as ASTM B117, thin dense chrome coating can withstand over 500 hours without base metal corrosion, which far outperform traditional hard chrome coating.
② Outstanding Hardness and Wear Resistance: The hardness of thin dense chrome plating is as much as that of hard chrome plating(800–1000 HV). Meanwhile, combined with uniformly dense microstructure and low friction coefficient, thin dense chrome plating provides excellent resistance to abrasive and adhesive wear.
③ Strong Adhesion: The coating exhibits good bonding strength with the plated metal, enabling it to withstand significant mechanical stress without delamination or spalling.
④ Minimal Influence on Dimension: Thin dense chrome plating is suitable for precision parts that require surface enhancement but has tight dimensional tolerance.
① High Cost: The cost of plating material is high due to specialized solution. And the process is complex for high precision, making the cost higher too.
② Limited Thickness: Although thin dense chrome coating is dense and wear-resistant, it is too thin to withstand conditions with high-level and long-term abrasion.
③ Difficult to Local Replating: Once thin dense coating has been damaged or worn, it is difficult to locally repair. Typically, it is required to strip off the entire coating and then replate. But the stripping process might damage the part.
3.3.2 Flash Chrome Plating
Flash Chrome Plating makes the coating highly glossy and mirror-like. And flash chrome coating is extremely thin. It is also mainly used for decoration, but even thinner than decorative chrome plating.
① Extremely Thin Coating: The thickness is about 0.05-0.5 μm.
② Highly Reflective Gloss: With dense and fine-grained structure, the coating can deliver an excellent mirror-bright finish.
③ Short Plating Process: The coating is so thin that the part can be coated much quickly.
① Appealing Appearance: Flash chrome plating can provide smooth and shiny finish for the part.
② Minimal Impact on Dimension: Since the coating is extremely thin, it has minimal impact on the part’s dimension.
③ Minimal Impact on Conductivity: Since the coating is extremely thin and uniformly complete, it has minimal impact on the conductivity for electric connectors etc.
④ Cost-effective: The coating can be plated quickly, making it suitable for components with certainly low requirements in batch.
① Relaying on Base Layer: It is usually required to plate a bright nickel plating as the base layer for flash chrome coating to improve gloss and durability.
② High Requirements for Base Layer: Because the surface defects of base layer cannot be concealed by the thin coating, it must keep highly smooth and finish.
③ Limited Durability and Corrosion Resistance.
3.3.3 Satin Chrome Plating
Different from the shiny and polished look of traditional chrome plating, satin chrome plating is matte or semi-matte and non-reflective.
The plating process typically uses standard chromium bath but it is required to brush the surface before plating to make it with soft satin texture.
And satin chrome plating is preferred by parts opt to subtle and elegant finish such as car parts, door handles, and kitchen utensils etc.
① The surface exhibits a soft silvery-gray tone with a subtle diffuse reflection.
② There are visible brush marks on the coating surface.
① With premium and understated finish, satin chrome plating is suitable for modern design.
② Satin chrome coating can effectively conceal fingerprints and fine scratches, making it resistant to dirt.
③ The surface is finely textured and silky smooth, making its touching feel more comfortable than that of highly polished surfaces.
④ The coating has moderate resistance to wear and corrosion.
① Although the coating can hide fingerprints well, it would be slightly difficult to clean stubborn stains from its micro-textured surface.
② Its durability is lower than traditional hard chrome.
③ It requires specific surface preparation to keep consistency.
3.3.4 Black Chrome Plating
Black chrome plating typically appears black or dark gray. It is not a single chrome coating but is combined with a black compound layer.
The coating is commonly produced by electrochemical method, during which the part plated with chrome coating would be immersed in a specialized plating bath. Then a thin film of chromium oxide would deposit on the surface, which is primarily composited with Cr₂O₃・xH₂O.
① The coating shows a matte dark finish with distinct metallic luster from conventional chrome plating. Its color is stable and highly resistant to fading.
② The black chromium coating is not pure chromium. Instead, it consists of chrome, chromium oxides, and fine chromium particles. Such a compound is the key for its black appearance.
① The matte black appearance is understated and elegant.
② The coating can effectively absorbs glare, making it suitable for optional instruments, camera lens barrels, and high-end automative interior components where reflections must be minimized.
③ The coating has moderate wear and corrosion resistance.
④ The coating is highly resistant to heat without discoloration or deformation.
① The process of black chrome plating is more complex than that of traditional chrome plating, making its cost higher.
② The color would vary based on plating parameters, which would affect consistency.
Chrome coating can be plated on various materials. The common materials are as follows.
Causes: ① Inadequate surface cleaning of oil, grease, or oxide scale
② Insufficient activation or exhausted activation solution
③ Improper current density (too high or too low)
④ Poor control of bath temperature or composition
⑤ Substrate issues like high carbon content or inclusions
Causes: ① High levels of impurities in the bath such as Fe³⁺, Cu²⁺, Cl⁻
② Too low or too high bath temperature
③ Incorrect current density
④ Imbalanced ratio of sulfate to chromic acid
⑤ Delayed rinsing during post-process or poor rinse water quality
Causes: ① Solid particulate contamination in the bath like dust and anode sludge
② Unrepaired surface defects such as scratches and pits of the part
③ Inadequate filtration of the plating solution
④ Hydrogen bubbles adhering to the part and not being dislodged
⑤ Insufficient wetting of the part before immersion
Causes: ① Uneven current distribution for complex parts
② Poor rack or fixture design
③ Insufficient cathode movement or solution agitation
④ Poor bath conductivity or low solution level
Causes: ① Excessive internal stress
② Excessive thickness
③ Excessively low bath temperature or high current density
④ Improper heat treatment to the part
⑤ Delayed or omitted hydrogen relief
Causes: ① Local electrical insulation for poor contact at rack
② Residual oil, oxide film, or passivation layer on the surface
③ Local anomalies of bath concentration or temperature
④ Power interruption or poor electrical contact
Causes: ① Incomplete rinsing after electroplating, leaving residual chromic acid
② Delayed drying, leading to surface oxidation
③ Contaminated by impurities in baths
④ Oxidated by excessive drying temperature
Causes: ① Toxic emissions and wastewater generated by hexavalent chromium plating
② Cr⁶⁺ is a known carcinogen, posing serious health and environmental damages
Maintenance of chrome-plated parts focuses on preventing oxidation/corrosion and physical scratches. Maintenance strategies should be tailored to their specific usage scenarios. Below is a detailed maintenance guide.
① Weekly Basic Cleaning:
Firstly, rinse the part thoroughly with clean water to remove dust and sand. And note that dry rub is not allowed, which would cause scratches.
Secondly, gently wipe the part with a soft sponge or microfiber cloth dampened with neutral car wash soap (pH 6–8). And note to pay special attention to positions where oil, insect residue, or grime accumulates.
Finally, completely rinse the part with clean water and immediately dry it with a clean absorbent towel since residual moisture would accelerate oxidation.
② Monthly Deep Maintenance:
Firstly, evenly apply chrome-specific protectant such as automotive chrome wax or silicone-based sealant over the surface after completely cleaning and drying.
Secondly, let it rests for 5–10 minutes, and then buff it shine with a clean cloth
This would form a film that shields against rain, UV rays, and environmental pollutants.
① Cleaning Every 2-3 Weeks:
Firstly, wipe dust away with a dry microfiber cloth. Note to do not use rough rags that cause micro-scratches.
Secondly, gently wipe the part by a cloth dampened with diluted neutral dish soap if there are light oil stains on it. And then dry it immediately with a clean cloth.
② Maintaining Every 3 Months:
For rarely used items plated with chrome coating, apply a tiny amount of petroleum jelly (Vaseline) or baby oil taken by a cotton swab. This creates a thin protective barrier against oxidation.
Firstly, dampen the oxidized area with water and apply a small amount of toothpaste to the cloth. Note that the toothpaste must be regular one with mild abrasives but not gel types.
Secondly, gently rub the area along small clockwise circles with light pressure for 1–2 minutes until the white spot fades.
Finally, rinse the part thoroughly to remove toothpaste residue and dry it completely. And apply chrome protectant afterward to prevent recurrence.
If the stains are bird droppings or tree sap, soak a cloth or cotton swab in warm water, and then place it over the stains for 5 minutes to soften them. Finally, gently wipe the part with neutral cleaner.
If the stains are heavy grease, dab a cotton swab with a small amount of 75% isopropyl alcohol or gasoline, and then gently clean the stains spot by spot. Note to avoid large applying in case of dissolving the protective film. And then rinse the part with water and dry it thoroughly.
Firstly, clean the scratched area to remove dust.
Secondly, apply a small amount of wax to the cloth and gently buff the scratched area along small clockwise circle with evenly light pressure and slow motion for 30–60 seconds.
Finally, wipe off residue with a clean cloth. If the scratch remains visible, repeat once or twice.
There are three main methods for chrome plating removal, including chemical stripping, mechanical removal, and reverse electroplating. It is required to choose the proper method according to the base material and specific properties of these methods.
① Commonly Used Solutions
Table of Commonly Used Solutions for Chemical Stripping | ||||
Solution
| Composition
| Temperature
| Immersion Time | Suitable Material
|
Dilute Hydrochloric Acid
| Hydrochloric acid (37% industrial grade) : Water = 1:1 to 1:3
| Room Temperature to 50°C | 10–30 minutes
| Steel (not suitable for copper)
|
Dilute Sulfuric Acid
| Sulfuric acid (98% industrial grade) : Water = 1:5 to 1:8
| 40–60°C
| 20–40 minutes
| Steel, Stainless steel
|
Chromic Acid–Sulfuric Acid
| Chromic anhydride (CrO₃) 100 g/L + Sulfuric acid 50 mL/L | Room Temperature | 30–60 minutes
| Copper, Copper alloys
|
② Procedure
Firstly, wipe the part with alcohol or acetone to remove oil, grease, and dust.
Secondly, prepare the stripping solution according to the specified formulation in an acid-resistant container like polypropylene plastic bucket or ceramic tank. And then immerse the whole part in the solution and gently agitate periodically.
Thirdly, observe the dissolving condition of the chrome coating. It will gradually flake off, and the solution will turn bluish-green or black.
Fourthly, as soon as the base metal becomes visible (when the steel appears silvery-gray or the copper appears reddish-purple), immediately pick the part out and rinse it thoroughly with clean water 3–5 times to eliminate all residual acid.
Finally, immerse the part in a mild alkaline solution for 5 minutes to neutralize any remaining acid. And then rinse it again with clean water, followed with drying by a clean cloth or hot air.
③ Key Precautions
① Tools and Procedure
Table of Tools and Procedure for Mechanical Removal | ||
Tool | Characteristics | Procedure |
Sandpaper (800–2000 grit)
| Coarse grit for plating removal with fine grit for polish
| 1. Lightly sand the chrome layer along one direction by 800-grit paper until the base metal is exposed. |
Angle Grinder with Flap Wheel
| Suitable for large areas or thick chrome layers
| 1. Install a 120-grit flap wheel and operate at low speed (≤1500 RPM) to gently contact the chrome surface. |
Ultrasonic Cleaner
| Ideal for tiny crevices and precision components
| 1. Fill the tank with water and a neutral degreaser, then submerge the part in it. |
② Key Precautions
① Procedure
Firstly, fill the acid-resistant plastic container with electrolyte.
Secondly, connect the part to the positive terminal as the anode, and connect a pure copper plate or graphite plate to the negative terminal as the cathode. Note to maintain a distance of 5–10 cm between the electrodes.
Thirdly, adjust the voltage to 5–12 V (higher voltage for thicker chrome layers) and the current density to 1–3 A/dm².
Fourthly, apply current and observe the stripping condition. Bubbles will form on the anode surface and the chrome coating will gradually dissolve. Note to turn off the power every 5 minutes to inspect the progress and continue until the chrome layer is completely removed.
Finally, turn off the power and pick the part out if the coating is completely stripped off. And then rinse the part thoroughly with clean water, followed by drying.
② Key Precautions
Comparison Table | ||||||
Feature
| Chrome Plating | Nickel Plating
| Powder Coating
| Anodizing
| Zinc Plating
| PVD
|
Hardness (HV)
| 800–1000
| 150–250(electroplating) | 20–100
| 300–600
| 70–150
| 1500–3000
|
Wear Resistance
| ★★★★★
| ★★★☆ (electroplating) | ★★
| ★★★☆
| ★★
| ★★★★★
|
Corrosion Resistance | ★★★★☆
| ★★★★
| ★★★★
| ★★★★
| ★★★☆
| ★★★★★
|
Environmental Friendliness
| ★
| ★★☆
| ★★★ (solvent-based) | ★★★★
| ★★★☆
| ★★★★★
|
Decorative Appearance | Excellent
| Good
| Excellent
| Excellent
| Fair
| Excellent
|
Cost | High | Medium–High | Medium | Medium | Low | High |
Substrate Compatibility
| Steel, copper, etc.
| Most metals
| Almost all materials
| Aluminum, magnesium, titanium | Ferrous metals
| Metals, ceramics
|
There are various finish techniques for different applications. Chrome plating standouts for its excellent hardness, corrosion resistance, durability and smoothly bright appearance. It is important to know these finish techniques comprehensively and choose the right one for applications. This article has provided a detailed guide of chrome plating. But if you still has question, contact with us freely.
Nickel plating is a kind of finishing technology that coats a thin nickel film onto allowable parts through electroplating or chemical methods. It can effectively enhance the substrate’s corrosion resistance, wear resistance, and electrical conductivity, and also can impart an aesthetically pleasing metallic luster for the surface.
Nickel plating has developed for a long history and gotten more and more various applications in these few decades. It can be traced back to the early 19th century by Luigi Brugnatelli’s nickel plating experiments in 1805.
And then through 30 years’ development, electroplating nickel plating has come into the world, by Golding Bird in 1837.
While, nickel plating got its most notable advancement in 1916 due to the invention of the Watts bath by Oliver P. Watts, within which nickel sulfate, nickel chloride, and boric acid are combined together to be a reliable technique for nickel electroplating.
Nickel plating has developed decades and still remains improved.
With excellent corrosion resistance, strong hardness, proper conductivity, and good wear resistance, nickel plating plays huge role in various industries such as automotive parts, daily hardware, and electronic parts etc.
Shall you have any CNC parts with nickel plating requirements, please contact ECOREPRAP. Fast quotation will be offered, stable quality with fast turn around service will be provided.
Lucas is a technical writer at ECOREPRAP. He has eight years of CNC programming and operating experience, including five-axis programming. He’s a lifelong learner who loves sharing his expertise.
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