Electroplating is a common surface finishing technique used in various industries for specific functions. It can provide the plated substrate with certain hardness, corrosion resistance, electrical conductivity, and wear resistance by plating a specific metal on its surface.
It is essential to have as much knowledge of electroplating as possible for the efficient production of metal parts.
Electroplating is a surface finishing process that involves coating one type of metal with a thin layer of another type of metal using an electric current. It is also known as electrodeposition.
Using the electrolysis principle, electroplating deposits a layer of metal or alloy on the surface to improve the material’s appearance, corrosion resistance, wear resistance, electrical conductivity, or other functional performance.
In fact, as long as the substrate is conductive, it can be electroplated.
Although metal remains the most common material for electroplating, as the autocatalytic coating technique advances, certain plastic parts can also be electroplated with metal layers.
During the electroplating process, the part to be plated serves as the cathode, while the plating metal serves as the anode. They will both be immersed in an electrolyte solution containing metal ions of the coating metal.
Actually, electroplating relies on redox reactions, during which one metal is oxidized at the anode while another metal is reduced at the cathode.
Once the direct current is applied, the metal cations in the solution will gain electrons at the cathode and be reduced to form a thin layer of metal coating.
At the same time, the metal atoms of the anode will be oxidized into ions and enter the solution as cations, replacing the deposited metal ions to maintain a stable concentration of metal ions in the electrolyte.
Common electroplating types include chrome, copper, nickel, zinc, gold, and silver. Each one has its own features and specific applications.
Since chromium is a chemically passive, dense, hard, and self-healing metal with a glossy luster, it is commonly used in metal electroplating to protect the metal substrate.
Chrome electroplating is usually divided into two types. One is decorative chrome electroplating, and the other is hard chrome electroplating. They are classified based on their different functions.
Decorative chrome electroplating is primarily used to make the part bright and mirror-like, enhancing its appeal. The coating is extremely thin on the top.
There are typically a copper undercoat and a nickel mediate coat beneath the chrome coat.
In fact, it is the nickel plating that provides the primary corrosion resistance, while decorative chrome plating is primarily used to further enhance the surface’s ability to prevent oxidation and discoloration.
Decorative chrome electroplating is commonly applied to automotive parts, such as wheels and grilles, as well as to sanitary ware, furniture, and consumer products.
Compared to decorative chrome coating, hard chrome electroplating is primarily used to enhance the surface’s mechanical properties, including hardness, corrosion resistance, abrasion resistance, and friction coefficient.
Hard chrome coating is typically much thicker than decorative chrome coating and is applied directly to the part surface.
It is commonly used on industrial machinery components, such as cylinder pistons and rollers, molds, tools, and other similar applications.
The plating solutions for chrome electroplating are typically divided into hexavalent chromium solutions and trivalent chromium solutions.
With severe toxicity, the former one is strictly restricted in many countries and areas. While the latter one is more environmentally friendly.
Related blog: What is Chrome Plating: Definition, Types, Process, Cost, Process and Application
Copper electroplating is also one of the most common electroplating methods. There are many advantages of copper electrocoating.
Firstly, copper electroplating can effectively enhance the part’s electrical conductivity.
Copper is an excellent electrical conductor and is widely used in electronic components, connectors, and printed circuit boards (PCBs) to enhance electrical conductivity.
Secondly, copper coating typically serves as an undercoat for other metal coatings within a multi-layer system. It can provide excellent adhesion and a smooth plate for subsequent coatings.
Thirdly, copper electrocoating can improve the surface’s ability to transfer heat.
And the solution systems for copper electroplating have three common types.
The most common one is sulfate copper plating, whose solution is composed of copper sulfate, sulfuric acid, chloride ions, and additives such as brighteners and levelers.
This system is commonly applied to PCB through-hole plating and as an undercoat layer for fast deposition, excellent conductivity, and low cost.
However, with certainly poor dispersibility, its coverage on complex parts is usually uneven, requiring additives to improve distribution and uniformity.
The second one is cyanide copper plating, whose solution is composed of copper cyanide, sodium cyanide, and sodium hydroxide.
Due to its good adhesion, this system is usually used as an undercoat for active metals such as steel and zinc alloys.
However, the solution is highly toxic. It has been gradually phased out by strict environmental regulations.
The final one is pyrophosphate copper plating, whose solution is composed of copper pyrophosphate and potassium pyrophosphate. This system is cyanide-free and environmentally friendly.
Furthermore, it exhibits good dispersibility, allowing for uniform coating on complex parts. However, the solution is certainly not stable. It needs a high cost for strict control.
There are three common types of nickel electroplating.
The primary one is Watts nickel plating, whose solution is typically composed of nickel sulfate, nickel chloride, and boric acid. The coating is usually bright or semi-bright, providing an appealing decorative effect.
Furthermore, due to its good ductility and adhesion, nickel electroplating often serves as an intermediate or base layer for subsequent coatings.
The second one is bright nickel electroplating.

With the addition of organic brighteners to the standard plating solution for Watts nickel, a brightly mirror-like surface can be obtained directly without the need for polishing. Therefore, it is widely used for decorative components in sanitary ware and household appliances.
The third one is black nickel electroplating whose solution is typically composed with nickel salt, zinc salt, sulfur compound, and boric acid. The coating is typically dark gray to black based on the solution formulation and current density.
And the coat has low reflectivity, so it is commonly used to optical instruments, military, and aerospace.
Moreover, its distinctive matte or satin black appearance can provide elegant and subtle decoration for electronic products and decorative items.
Related blog: What is Nickel Plating?
The plating solution for zinc electrocoating is usually zinc sulfate, zinc chloride, or cyanide zinc.
Compared with other metal coatings, zinc coating is a kind of sacrificial protection. Even if the coating is locally damaged, the exposed steel can still be protected by the remaining zinc. This can improve the part’s durability and service life.
In addition, zinc plating can provide various appealing appearance. The coating surface is usually smooth and can be designed in patterns and passivated in different colors.
What’s more, the zinc electrocoating can bond tightly to the base metal. Even during operations such as rolling, drawing, or bending, that can alter shapes, the coating is not prone to peeling or damage.
And zinc is also a conductive metal coating.
Color zinc plating is primarily distinguished by the surface color formed after passivation, including blue-white zinc, yellow (rainbow) zinc, and black zinc.

These colors do not represent different zinc-plating processes, but rather the passivation treatments applied to the zinc layer after electroplating.
Zinc electroplating is widely applied to the automotive industry, electronics, and construction hardware.
Related blog: Zinc Plating – Everything You Shall Know
There are three common types of gold electroplating based on the appearance and composition.
The primary one is yellow gold electroplating. Gold is the most classic and common color for gold electroplating.
Yellow gold electroplating typically uses high-purity gold and sometimes adds small amounts of silver or copper to finely adjust color and hardness.
It typically exhibits a warm, bright yellow tone reminiscent of natural gold. And due to its chemical stability, pure gold is extremely resistant to oxidation and discoloration.
Therefore, pure gold electroplating is widely used in jewelry and accessories, such as necklaces, rings, and watches.
What’s more, pure gold has extremely low electrical resistance.
As one of the best conductive materials, pure gold is commonly used in wire bonding, electronic connectors, and semiconductor applications.
And pure gold is much softer, with poor wear resistance.
The second one is white gold electroplating. It is designed to mimic the appearance of natural platinum. Platinum electroplating is expensive, so it is rarely used for ordinary decorative purposes.
Actually, white gold electroplating is a type of alloy coating whose gold plating solution typically contains white metals, such as nickel and palladium.
It typically appears silver-white or bright white with a cool-toned luster, offering a more modern look compared to traditional yellow gold.
Additionally, to achieve a brighter and purer white appearance, rhodium plating is usually applied to many white gold coatings. Rhodium is extremely hard and highly resistant to oxidation.
Among white gold electroplating, the Au–Ni alloy is the most common type, which contains 75%–90% gold with the remainder being nickel , providing a white color and hardness.
While Au–Pd alloy is the most high-end option, offering better corrosion resistance, it is commonly used in elevated jewelry to avoid nickel allergies.
Among the three types of gold electroplating, white gold electroplating often exhibits the highest wear resistance, thanks to the excellent scratch resistance provided by rhodium plating.
The hardness and corrosion resistance of white gold electroplating are also excellent. It exhibits worse electrical conductivity than pure gold, but remains acceptable.
The third one is rose gold electroplating. It has become increasingly popular in recent years, favored for its soft and romantic hue. Rose gold electroplating is a type of alloy composed of gold and copper. It typically exhibits a soft pink or reddish gold hue, falling between the tones of yellow gold and copper.
The color of rose gold electroplating is achieved by adjusting the copper content in the gold plating solution. Higher copper proportion leads to a deeper red hue.
The standard rose gold plating, also 18k gold electroplating, is typically composed of 75% Au, 22.25% Cu, and 2.75% Ag. It is the most common rose white electroplating, widely used for watches, wedding rings, and mobile phone accessories.
While the 22k rose gold electroplating is pink gold electroplating with softer and more elegant appearance. It is usually composed with 91.7% gold, 7-8% copper, and 0.5-1% Ag, commonly applied to luxury jewelry and accessories.
And the 14k rose gold electroplating typically appears deep red or copper red with high saturation. It is often composed of 58.3% gold, 35-40% copper, and 1-2% Ag.
With a higher copper content, the coating’s hardness would be enhanced, and its color would be more intense; however, it is also prone to oxidation and darkening. It is also widely used to fashion accessories at a much lower cost.
The hardness and abrasion resistance of rose gold electroplating are worse than those of white gold electroplating and better than those of yellow gold electroplating.
While its corrosion resistance is worse than that of both white gold and yellow gold. Copper is easier to oxidize and also has higher electrical resistance.
During the common silver electroplating process, the part to be plated acts as the cathode, and a piece of pure silver acts as the anode.
They are both immersed in an electrolyte containing silver ions, typically a potassium silver cyanide solution. When the direct current is applied, the silver ions are reduced and deposited on the surface.
There are various features of silver electroplating. Firstly, silver has the highest electrical conductivity among all metals.
Therefore, silver plating is widely used in electrical and electronic components to enhance the conductivity of contacts and connectors.
Additionally, silver exhibits has good solderability, which facilitates connections for electronic components.
Secondly, with a specially appealing luster and good corrosion resistance, silver electroplating is widely used for tableware, jewelry, handicrafts, and musical instruments.
Thirdly, silver has high reflectivity for visible and infrared light, so silver electroplating is widely used in reflecting mirrors and optical devices.
However, if the silver is exposed to an environment containing sulfur, black Ag₂S forms on the surface.
Silver is soft with normal wear resistance, usually coated with nickel to improve performance.

Composed with the similar metal intended for deposition, the anode acts as the sacrificial source of metal ions. Through controlled anodic dissolution, it can provide positively charged metal ions to the surrounding electrolyte.
And because of the cathode’s negative charge, it would attract the positively charged metal ions within the electrolyte bath. Then a thin layer of metal coating would deposit on the surface.
The electrolyte must be conductive to ensure the proper flow of electricity between the anode and cathode. In addition, it usually contains a dissolved salt of the metal to be deposited for continuous supply of object metal ions.
What’s more, it is crucial to strictly control the key processing parameters such as current density, temperature, pH level, and agitation, which would significantly influence the plating rate and quality.
There are four types of common methods for electroplating. Each of them has special features, advantages, and disadvantages. It is suggested to choose the proper one based on the products.
By rack plating, a single part or multiple parts will be secured on the conductive rack. Then the whole rack will be suspended in the plating bath as the cathode.
As the current is applied, electroplating develops. In addition, the rack is usually specifically designed.
Features of Rack Plating
Advantages of Rack Plating
Disadvantages of Rack Plating
For barrel plating, a large quantity of small parts would be placed into a perforated rotating barrel ((typically hexagonal or cylindrical in shape and made of PP, PVC, or titanium).
Then the barrel will be immersed in the plating bath as the cathode. As the barrel slowly rotates, the parts tumble continuously for uniform metal deposition.
Features of Barrel Plating
Advantages of Barrel Plating
Disadvantages of Barrel Plating
Reel-to-reel plating is a highly automated plating method specifically designed for continuous strip or wire materials. During the process, coiled metal strips or wires would be continuously fed into the plating bath vis guide rollers for coating.
Features of Reel-to-Reel Plating
Advantages of Reel-to-Reel Plating
Disadvantages of Reel-to-Reel Plating
Brushing plating is a specialized portable electroplating method that does not require immersing the entire part in the electrolyte.
For brushing plating, a plating brush dipped with plating solution would be moved locally over the part surface that serves as the cathode.
As the direct current is applied to the part, it will be selectively electroplated in the plating solution. The plating brush is typically made of graphite, stainless steel, or cotton-wrapped anode.
Features of Brushing Plating
Advantages of Brushing Plating
Disadvantages of Brushing Plating
Applications:
Repairment for shaft parts such as hydraulic rodsand motor shafts; Local requirement for molds; on-site maintenance for large equipment such as ships and wind turbine gears; surface hardening for printing rollers etc.
The key to electroplating lies in the material’s electrical conductivity.
Most metal materials is conductive and can be electroplated. Some passive metals should be activated first before electroplating to enhance adhesion.
What’s more, for certain materials without electrical conductivity, chemical plating should be applied first to make them conductive.
Steel materials such as carbon steel, stainless steeland cast iron are the most commonly electroplated materials, typically coated with zinc, nickel, or chromium to improve corrosion resistance and decorative appearance.
Copper materials such as brass and bronze have excellent electrical conductivity. They are commonly used as an undercoat or directly plated with gold or silver for electronic components.
Aluminum is a kind of passive metal on which there would always be a hard and passive oxide layer. Such a passivated coating would lead to poor adhesion for direct electroplating.
Therefore, special pre-processes such as zincate treatment or anodizing plating are required before electroplating.
Zinc and its alloys are commonly used for decorative electroplating on die-cast parts in automotive and hardware industries.
They typically require a multiple coating system, a copper layer first, and then a nickel layer, finally followed by a decorative or functional chrome coating.
Magnesium and magnesium alloys are important in the aerospace and automotive industries due to their low weight.
They are electroplatable but require highly sensitive pretreatment and intermediate layers due to their active surface.
There would always be an oxidation layer(MgO) on the magnesium surface when exposed to water or air, which is insulating and has poor adhesion.
In addition, magnesium is much easily to be dissolved or corroded by plating solutions, especially acidic ones.
Before electroplating, it is required to pretreat magnesium parts primarily to change its active surface and plate a strike coating on the surface.
Firstly, the oxide film on the magnesium surface must be removed through mild pickling by special chromic acid or phosphoric acid solutions. And note to avoid excessive attack in the meantime.
Secondly, immerse the part in a weakly alkaline or neutral zinc salt solution. A thin and dense zinc immersion layer would form on the magnesium surface through a chemical displacement reaction.
The two steps can help to isolate the magnesium surface from the plating solutions and prevent corrosion, and to provide a conductive and well-adhering intermediate layer.
Thirdly, electroplate a non-acidic underlayer, typically cuprous pyrophosphate or mildly alkaline nickel on top to seal and protect the zinc layer since the zincate layer is very thin and still highly reactive.
Note to plate a properly thick coat to ensure complete isolation between the magnesium substrate and the main plating solutions.
Finally, the common electroplating processes can be applied to the part.
Titanium and its alloys are widely used in aerospace and medical implants due to their excellent hardnessand corrosion resistance, as well as light weight.
Electroplating is applied to titanium parts usually for special functions such as good electrical conductivity and friction
However, it is certainly difficult to electroplate titanium parts. Titanium would instantly form a very dense and chemically stable titanium dioxide film(TiO₂) in air.
This layer is highly insulating and chemically inert, which fundamentally prevents strong adhesion for electroplating.
The key to electroplate titanium lies on removing the oxide layer and establish an instantaneous conductive path.
It is required to use highly corrosive agents for pickling to dissolve or thin the oxide layer. And the process must be strictly controlled to prevent over-etching.
Then a copper or nickel undercoat is needed. You can take advantage of the strong complexing ability of fluoride ions to deposit a copper or nickel plating on the surface at extremely elevated temperature.
Or you can used special nickel or copper strike plating by short current to deposit metal atoms rapidly on the surface at the instant when the oxide layer is dissolved.
Finally, you can apply common electroplating on the surface.
Plastics are becoming increasingly popular in the industry for their lightweight nature and low cost, although metals remain the dominant materials.
However, nowadays, a combination of 3D-printed parts with electroplating is increasingly used in various industries for design freedom and good protection.
Certain plastics, such as ABS, PC/ABS, and PP plastics, are electroplatable as long as they are properly pretreated.
Below is a photo of plastic 3D-printed parts in decorative chrome electroplating.
The key to electroplating plastics lies in electrical conductivity.
There are three crucial steps before electroplating 3d prints.
Firstly, it is necessary to chemically etch the plastic part by immersing it in a strong oxidizing solution, typically a mixture of chromic acid or sulfuric acid.
This would create tiny and uniform pits on the surface to enhance the mechanical adhesion between the part and plated layer.
Secondly, activate the part by immersing it in a solution containing palladium and chloride ions.
The palladium ions would be adsorbed onto the microporous surface and reduced to colloidal palladium nuclei. The surface is then uniformly covered with catalytically active palladium particles.
Thirdly, electroless plating must be applied to the plastic surface to make it conductive. It is required to immerse the part in a plating solution containing nickel or copper salts.
The metal ions in the solution would be reduced to metal atoms under the catalytic action of the palladium nuclei and deposit on the surface as an entire layer.
Therefore, the plastic surface is now coated with a thin, uniform layer of copper or nickel, transforming the surface from an insulator to a conductor.
Finally, common electroplating can be applied to the plastic surface. However, there are also some plastics that cannot be electroplated, such as PE, PTFE, PVC, PS, and PC plastics.
Electroplating coatings can effectively isolate the base metal from the corrosive media such as water, oxygen, and salts to lengthen the part’s service life.
Electroplating can make the part’s surface much brighter, smoother, and more uniform. Gold electroplating, silver electroplating, bright nickel and decorative chrome electroplating are usually used to make the part more appealing.
Certain hard coatings such as hard chrome plating, nickel phosphorus alloys, or composite electroplated coatings, can significantly increase the surface hardness and wear resistance of parts, making them suitable for components that must withstand friction.
Plating metals that are highly conductive, such as gold, silver or copper, onto electronic components or connectors can reduce electrical resistance and ensure the reliability and efficiency of signal transmission.
By depositing additional metal on the part’s surface, electroplating can help to increase the dimensionof worn part.
It is known that strong acids and alkalis as well as heavy metal salts are commonly used in electroplating processes.
If the wastewater and sludge are not properly treated, they can cause severe environmental pollution.
This requires companies to invest in costly equipment and treatment for environmental protection.
For parts with complex geometries, the currentdistribution would usually be uneven, which can lead to thicker coating at sharp edges while thinner or even absent coating at recesses.
During the electroplating process, hydrogen atoms may diffuse into the substrate, leading to hydrogen embrittlement, especiallyfor high-strength steels.
This would cause worse resilience and higher brittleness. Therefore, specific treatment to remove hydrogen is required to mitigate this issue for no cracking risk.
Electroplating processes often involve long processing time, complex bath formulations, strict temperature and current control, and the use of expensive raw materials. As a result, the overall cost tends to be relatively high.
Reverse electroplating is actually electropolishing during which a thin metal layer would be dissolved from the surface by direct current. While electroplating is a deposition process.
Platinum electroplating is a electrochemical process during which a thin layer of platinum metal would deposit on the base surface.
Platinum is a rare precious metal that has extremely excellent corrosion resistance to nearly every chemical substance. It also has brilliant conductivity, catalytic activity, and biocompatibility. What’s more, it appears bright white with appealing appearance.

Lucas is a technical writer at ECOREPRAP. He has eight years of CNC programming and operating experience, including five-axis programming. He’s a lifelong learner who loves sharing his expertise.

Chrome plating, or chromium electroplating, is a surface finishing technology that deposits a layer of chromium onto a metal or plastic surface through an electrolytic process.

Zinc Plating are classifed into Hot-Dip Galvanizing, Electro Zinc Plating,Mechanical Zinc Plating and Electroless Zinc Plating.

Nickel plating is a kind of finishing technology that coats a thin nickel film onto allowable parts through electroplating or chemical methods. Two main types: Electroplating Nickel (EN) and Electroless Nickel Plating (ENP).

Electropolishing is an electrochemical process that removes microscopic surface peaks from metals, resulting in a mirror-like smooth finish, enhanced corrosion resistance, and reduced risk of contamination.